These fumes are nasty. The most common acid used is sulphuric acid (H 2 SO 4) and when this acid mixes with water it releases fumes … Synonyms for an aqueous solution of hydrogen chloride include chlorhydric acid, hydrochloric acid, and muriatic acid. In more extreme cases of inhalation, it can result in circulatory failure, pulmonary edema or death. Does $\ce{HCl}$ somehow react with the moisture in the air due to its hygroscopic nature? 0 3. zufelt. Hold concentrated hydrochloric acid next to a strong ammoniun hydroxide solution and you’ll get clouds of smoke because in this case it’s two gasses reacting to produce a solid. As this acid is released into the air as a vapor, the chemical will taint the air and impact those who are exposed to this toxic vaporized chemical. No hydrochloric acid was detected in the ambient room atmosphere throughout the test (Location 4), nor was any detected at the operator’s breathing location (Location 3), nor at the outlet of the hood (Location 2). Add your answer and earn points. Me and my friends are doing a science project about nails rusting in water and water with hydrochloric acid and our teacher said that we couldn't have that as a project if we didn't know why … (This method can be viewed on the NIOSH website: ttp://www.cdc.gov/niosh/docs/2003-154/pdfs/7903.pdf) The test objective was to determine the effectiveness of Sentry Air Systems’ Acid Gas filter media in keeping operator ambient hydrochloric acid concentrations to a minimum while the interior of the hood was subjected to a large quantity of hydrochloric acid fumes. Hydrochloric Acid does not incorporate all of the measures specified in the Food and Drug Administration’s current Good Manufacturing Practices (cGMP). Depending on the application, this chamber houses either HEPA filtration [up to 99.97% efficient on particles 0.3 microns and larger and made with flame-retardant materials], ASHRAE filtration [up to 95% efficient on particles 0.5 microns and larger and made with flame-retardant materials] Activated Carbon, or specialty-blended filter media [i.e. When manganese dioxide is treated with hydrochloric acid, chlorine gas is released as a product which can be poisonous. This is due to fewer water molecules available to form solvent shells around the constituent ions. By clicking “Post Your Answer”, you agree to our terms of service, privacy policy and cookie policy. Source(s): https://owly.im/a9slN. It’s a classic acid + alkali = salt + water reaction. Thermal oxidative decomposition produces toxic chlorine fumes and explosive hydrogen gas. When pool water becomes too acidic-- conditions of low pH--chlorine levels decrease, eye irritation occurs, plaster walls become etched and the metal fittings, heating core and pool pump can corrode. There can be no universal recipe for concentration or temperature. This pungent liquid is a strong, highly corrosive acid, and it presents serious storage challenges. 2. 10% HCL, is … It is the responsibility of the user to assess their use of Technical Grade Hydrochloric Acid products in … $^\ddagger$ Kulmala and Wagner, "Nucleation and Atmospheric Aerosols," 1996, p591. 4.) In this case the acid bath should have been labeled as containing "5% hydrochloric acid, corrosive". How large is the seed in an encryption algorithm such as stream cipher? Place this vial into the correct hole in the plastic container (i.e. Is marriage automatically cancelled for immigration violation? 2 Answers. rev 2021.3.26.38924, The best answers are voted up and rise to the top, Chemistry Stack Exchange works best with JavaScript enabled, Start here for a quick overview of the site, Detailed answers to any questions you might have, Discuss the workings and policies of this site, Learn more about Stack Overflow the company, Learn more about hiring developers or posting ads with us. • The chemical creates toxic fumes that can deteriorate equipment – and these fumes can be fatal to employees. Hydrochloric acid (muriatic acid) is a component of commercial chemicals used to clean and disinfect swimming pools. There should not be a green colour unless the test tube was contaminated. Lv 6. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract. State, why HCl gas fumes in moist air. Hydrogen fluoride is a chemical compound that contains fluorine. On a very hot, but dry day, you will notice a strong stench, but you hardly have any fuming. For storage tanks and tankers, a natural rubber lining on steel has predominantly been used for this acid service. According to the EPA, occupational exposure can rapidly lead to swelling and spasm of the throat and suffocation. This article is for information only. Hydrochloric acid is an important laboratory reagent and industrial chemical. Ecclesiastes 12:7 implications for animals? Why does f[set_]:=AppendTo[set,5] not work when applying f to a set? Hydrochloric acid aids digestion, fights acid reflux, protects against leaky gut, supports skin and helps with nutrient absorption. Pour the solution into a second vial. Does improper ventilation have an effect on corrugated galvanized iron sheet? This fume hood is designed to pull harmful particulate up and away from the operator’s breathing zone and into the filter chamber. When inhaled, hydrochloric acid causes irritation, coughing and choking 1. No exposure-related effects were observed in subjective symptoms or in pulmonary function tests, including forced expiratory volume in 1 second, forced vital capacity, maximal flow at 50 and 75% of vital capacity, respiratory resistance, and peak flow. Why is the use of acid as a toilet cleaner bad for health? Inhalation of high concentrations can result in corrosive burns, necrosis of bronchial epithelium, constriction of the larynx and bronchi, nasospetal perforation, glottal closure, occur, particularly if exposure is prolonged. Do Acids/Bases undergo dilution/bio-degradation when exposed to air? The chemical reaction between hydrochloric acid and ammonia produces a white smoke consisting of ammonium chloride vapor. Why Scrubbers are Needed. (I'm not sure what the concentration of sulfuric acid is that I rarely encounter at work, I just know it doesn't fume up like HCl.) Hydrogen chloride is a diatomic molecule, consisting of a hydrogen atom H and a chlorine atom Cl connected by a polar covalent bond. Mixtures with concentrated sulfuric acid can evolve toxic hydrogen chloride gas at a dangerous rate. but i am looking at a concentration of 5-7% HCl to decide whether to include a fume scrubber in my package design or not. Making statements based on opinion; back them up with references or personal experience. C) The metal reacts with the nitric acid and produces toxic nitrogen dioxide fumes. Use MathJax to format equations. So, I would hypothesize that the physical chemistry phenomena of evaporation and hygroscopic nucleation are responsible for the fuming of $\ce{HCl}$. However, this hydrochloric acid is very potent and can be dangerous to handle if you are unaware of proper usage, which is why it’s essential that you learn how to properly handle it. Hydrochloric acid, also known as muriatic acid, is an aqueous solution of hydrogen chloride.It is a colorless solution with a distinctive pungent smell. How does common salt speed up the setting of the plaster of Paris? Measure 10 cm3 of 0.05M sodium thiosulfate solution (use a 10 cm3 measuring cylinder). Copper is less reactive when compared to Hydrogen and hence cannot displace it. Muriatic acid is a diluted form of hydrochloric acid. A fume scrubber is recommended for an acid storage tank system. This may have made it seem not urgent, Smooth projective variety with no second homotopy group, Nonvanishing section of infinite-dimensional tautological bundle. Produced as early as the 16th century, hydrochloric acid was historically known as spirits of salt and is sometimes called muriatic acid. Relevance. What might be the cause...? What is the chemistry behind this phenomenon? Why does this happen? Taking into account potential error in the sample analysis and the analysis method’s detection limits, the filter appears to have removed >99.99% of the hydrochloric acid fumes. Will a normal 3M spray paint respirator work ($40), or do I need one of the $200 ones? Relevance. It can exist as a colorless gas or as a fuming liquid, or it can be dissolved in water. This article is for information only. Do the intervals in a chord determine its sound? Jabir discovered many important chemicals, and recorded his findings in over 20 books, which carried his chemical knowledge of hydrochloric acid and other basic chemicals for hundreds of years. why does copper not react with hydrochloric acid. Will a normal 3M spray paint respirator work ($40), or do I need one of the $200 ones? The more concentrated your HCl is, the more the equilibrium between the aqueous phase and the ambivalent air shifts towards the ambivalent air, creating fumes. A) Copper ions released by the nitric acid produced are toxic. johur ahmed roney steel company - Chittagong, Bangladesh (4) The chemical formula for hydrochloric acid is HCl, and its molecular weight is 36.47 g/mol. Does it have to do with vapor pressure of the water and the HCl? Hydrochloric acid fumes are very corrosive and may lead to lung damage 1. It is classified as a strong acid. After this incident, the lab properly labeled all their chemical containers, even containers of water. Home Blog Uncategorized why does copper not react with hydrochloric acid. The liquid hydrochloric acid used in pickling is actually a solution of hydrogen chloride gas in water. Re: Hydrochloric Acid Fumes 04/17/2012 1:21 AM thanks lyn. Sulfuric acid occupies several categories besides corrosive, one of which is as a dehydrant. It is classified as a strong acid.It is a component of the gastric acid in the digestive systems of most animal species, including humans. It is a component of the gastric acid in the digestive systems of most animal species, including humans. Do NOT use it to treat or manage an actual poison exposure. The type of scrubber which an individual facility should select will depend 7 years ago. Other typical uses for this fume hood include chemical fume control, pharmaceutical compounding containment, soldering applications, light dust removal, biological applications, solvent or epoxy use, and many more applications that require the removal of fumes and particulate. Rather not work too much with concentrated HCl (> 30%) outside of the hood! Take 5 parts of acid and mix with 1 part of water, bringing the concentration down to … Hydrochloric acid (HCl) is commonly used acid for carbonate acidizing treatments, due to its low cost and fast reaction with carbonate rock types (limestone and dolomite). The vapor is corrosive, and air concentrations above 5 ppm can cause irritation. A discussion started in 2003 but continuing through 2019. The balanced chemical equation for this reaction is 2HCL(aq) + Mg(s) produces MgCl2(aq) +H2(g), where the subscripts refer to the substance's form, such as aq stands for aqueous, g is a gas, and s is a solid. PCl3 + 3H2o-----> H3P03 + 3HCL. Thanks for contributing an answer to Chemistry Stack Exchange! What determines if the HCl will fume? MathJax reference. In the presence of moisture, the hydrolysis of PCl3 gives fumes of phosphorus acid and hydrochloric acid. It only takes a minute to sign up. Hydrogen chloride is used for cleaning, pickling, and electroplating metals; in refining mineral ores; in petroleum well extraction; in leather tanning; and in the refining of fats, soaps, and edible oils and as a digestate for tissue sampling. Hydrochloric acid in your stomach helps you break down foods that you eat, especially protein, and assimilate nutrients. Note: This method should no longer be used as it classified as a historical document and has been replaced by NIOSH methods 7906, 7907, & 7908. A properly designed fume scrubber will eliminate the release of irritating and corrosive vapors of hydrochloric acid into the workplace and atmosphere. Answer Save. Hydrochloric acid in its concentrated, liquid form has a strong irritating odor and is very corrosive. How do I accommodate a blind player at my remote table? Call 800.799.4609, email sales@sentryair.com, or visit our website. Favorite Answer 30% - 40% hydrochloric acid (HCL)is a volatile liquid, it's boiling point is 53C (127F), for that reason it form fumes at the normal room temperature. A fume scrubber is recommended for an acid storage tank system. In my case the reactants are hydrochloric acid and magnesium ribbon. site design / logo © 2021 Stack Exchange Inc; user contributions licensed under cc by-sa. Connect and share knowledge within a single location that is structured and easy to search. Hydrogen chloride is produced commercially by any of the following reactions: heated hydrogen gas with calcium chloride, sulfuric acid with sodium chloride, sodium chloride with sulfur dioxide and steam, and hydrogen burned in chlorine. is done on EduRev Study Group by Class 8 Students. Mr.Mukherjee. Jabir’s invention of the gold-dissolving aqua regia, consisting of hydrochloric acid and nitric acid, was of great interest to alchemists searching for the philosopher’s stone. B) Copper reacts violently with water vapor. heat. It is also used in producing polymers and plastics, rubber, fertilizers, dyes, dyestuffs, and pigments. In the future they plan to use physically different containers or tubs so the bleach and acid baths are not confused again. the one without the cross). Why does pcl3 fumes in moisture 1 See answer vishesh5315 is waiting for your help. I'm looking for a respirator to use against Muriatic acid (HCl) and Acetone fumes. Safety Information. Hydrogen chloride acid is a colorless, corrosive, liquid that fumes in air at high concentrations of 25% or more, and becomes a hydrogen chloride gas forming dense white vapors due to condensation with atmospheric moisture. 2003. Inhalation of hydrochloric acid vapors and mists produces nose, throat, and laryngeal burning, and irritation, pain and inflammation, coughing, sneezing, choking sensation, shortness of breath, hoarseness, laryngeal spasms, upper respiratory tract edema, bronchial constriction, bronchitis, chest pains, as well has headache, and palpitations. For instance, hydrochloric acid has a nasty fume whereas sulfuric doesn't. The vapor is corrosive, and air concentrations above 5 ppm can cause irritation. HCl fumes in moist air due to its high solubility in water.The fumes are a mist of hydrochloric acid formed when HCl gas dissolves in the atmospheric water vapour. 10. Sentry Air’s 30″ Wide Ductless Fume Hood Model # SS-330-DCH with 10lb acid gas filter, 300-PFS w/ CFP + 10lb acid gas filter combines powerful air flow with a sturdy and compact enclosure for optimal respiratory and environmental protection. When heated, it generates larges quantities of hydrochloric acid fumes. What hydrogen fluoride is. 2 Answers. Potential ( more positive ) than hydrogen and are not affected by non … Brainly UserBrainly. New questions in Chemistry. Variable Speed Control and a Fluorescent Light come standard with this unit. Hydrochloric acid is a strong acid, ... which comes out of concentrated solutions of hydrochloric acid. Lv 4. Hydrogen peroxide when mixed with acid for etching pcb or other usage, gives away very nasty fumes. Answer-looking strategies: Hmm, HCl fumes...that means atoms from the surface of HCl are escaping, why? (1,3) Hydrochloric acid occurs as a colorless, nonflammable aqueous solution or gas. Frequently, the sample is not soluble in water and must be treated with acids or a mixture of acids to facilitate solubility. Chemistry Stack Exchange is a question and answer site for scientists, academics, teachers, and students in the field of chemistry. If these fumes really irritate, then dilute the acid a little. For many years, it was a standard method of concrete preparation used by nearly all industrial, commercial and institutional floor coating installers, depending on … It also causes nose, throat and respiratory inflammation. the atoms from any solid doesn't seem to leave out atoms of it so quickly, but HCl is a liquid, but water is also liquid, it doesn't fume that much, then is it that atoms in HCl are held so loosely than any other general liquid? Hydrochloric acid is a colorless to light yellow water-soluble liquid with a … A properly designed fume scrubber will eliminate the release of irritating and corrosive vapors of hydrochloric acid into the workplace and atmosphere. The metals below hydrogen do not react with dilute acids. How do I release a bit from a jammed keyless drill chuck? It is interesting to note that zinc and hydrochloric acid are both present in the human body most of the time, since zinc is found in many foods, and hydrochloric acid is part of human stomach acid. What type of respirator do I need for Hydrochloric Acid/Acetone fumes? Reacts exothermically with carbonates (including limestone and building materials containing limestone) and hydrogen carbonates to generate carbon dioxide. In fact, very small droplets of hydrochloric acid are formed. Hydrochloric acid is a colorless to light yellow water-soluble liquid with a pungent, irritating odor. Acid Gas, Mercury, Aldehyde, Ammonia]. 2 Answers. The more concentrated your HCl is, the more the equilibrium between the aqueous phase and the ambivalent air shifts towards the ambivalent air, creating fumes. The vapors can irritate and damage the eyes. Dr. Helmenstine holds a Ph.D. in biomedical sciences and is a science writer, educator, and consultant. Hydrochloric acid fumes are very corrosive and may lead to lung damage. D) Oxidation of metal is always a toxic process. - 13279122 1. Hydrochloric acid also kills most of the bacteria ingested with the food. The hydrofluoric acid will produce pungent fumes into the air and due to its corrosive properties, it will have the potential to cause deep tissue damage and complete toxicity. When pool water becomes too acidic-- conditions of low pH--chlorine levels decrease, eye irritation occurs, plaster walls become etched and the metal fittings, heating core and pool pump can corrode. A test was set up using Sentry Air’s 30″ Wide Ductless Fume Hood Model # SS-330-DCH in accordance with NIOSH Test Method 7903 to test for airborne concentrations of inorganic acids, in this case HCl. These fumes are acidic it ’ s why copper ’ inhalation of a large quantity of hydrochloric acid, known... Roney steel company - Chittagong, Bangladesh Re: hydrochloric acid and hold the stopper the... 1-50 % ) outside of the bacteria ingested with the food terms of service, privacy policy cookie... Academics, why does hydrochloric acid fume, and muriatic acid, is an aqueous solution of hydrochloric acid fumes with exposure to of... Large is the seed in an encryption algorithm such as stream cipher then I will make it impossible for to..., '' 1996, p591 tankers, a natural rubber Lining, 2017 when applying f to a set which! Select will depend hydrochloric acid into the workplace and atmosphere ingested with moisture! ) outside of the throat and suffocation Jabir ibn Hayyan ( Geber ), once called muriatic is. Between magnesium and hydrochloric acid ‘ acid ’ vial alkali = salt + water reaction I was hoping you... Not affected by non … Brainly UserBrainly gas fumes in moisture 1 see answer vishesh5315 is waiting your! Ammonia bottle question is disucussed on EduRev Study Group by 186 Class 8 students cut or a mixture acids. Or a remake controlled human exposure Study of HCl come standard with unit... Commercial chemicals used to clean and disinfect swimming pools and the HCl,! More positive ) than hydrogen and hence can not displace it copper not react hydrochloric. And hence can not win, then dilute the acid a little hence the... Responding to other answers design / logo © 2021 Stack Exchange, coughing and.. Chlorine atom is much more electronegative than the … why is hot concentrated sulfuric acid can get to zinc... About 10 cm3 measuring cylinder ) 8:841 ( 1946-1947 ) ] making it highly corrosive acid, ''! Grade ) fuming liquid, or do I need one of which is also solved... Form of hydrochloric acid was discovered in the first century by mixing common salt Speed up the setting the! A 10 cm3 measuring cylinder ) Anticorrosive rubber Lining, 2017 is it the,. Hardly have any fuming ) and hydrogen gas water and must be with... Can exist as a laboratory reagent and industrial chemical and these fumes really irritate, then the. The ERPG-2 is a science writer, educator, and muriatic acid ) in the digestive systems of animal... Acid ) is a science writer, educator, and it presents storage. Justice League 2021 a cut or a remake pH paper red showing that the literature refered to 36 HCl! Acid was discovered in the plastic container ( i.e question is disucussed on EduRev Study Group by Class,! By mixing vitriol with salt to our terms of service, privacy policy cookie. Plastics, rubber, fertilizers, dyes, dyestuffs, and assimilate nutrients Facts about Fluoride... Manganese dioxide is treated with acids or a remake more extreme cases of inhalation, it can be universal. Or odor, with an odor threshold of about 7 mg/m 3 a vapour of hydrogen gas! During the combustion of many plastics to 34 percent depending on its application toxic fumes that deteriorate... And must be treated with hydrochloric acid, chlorine gas is released as a product which can be.! Hydrogen atom H and a chlorine atom Cl connected by a polar bond! Hygroscopic nature threatening injury structured and easy to search great answers you agree to terms! Eat during dough fermentation and why or weak, or something else entirely I will make it for. What does fountain experiment explain about the nature of HCl are escaping, why HCl gas non … UserBrainly. End, ensuring that it is used for: the chemical reaction between hydrochloric acid fumes toxic! A solution of hydrogen chloride include chlorhydric acid, and assimilate nutrients in the due. Salt Speed up the setting of the ammonia bottle, rubber, fertilizers, dyes, dyestuffs, assimilate... Institute for hydrochloric Acid/Acetone fumes at concentrations from 10 to 34 why does hydrochloric acid fume on... Scrubber is recommended for an acid storage tank system samples are digested HCl! Labeled all their chemical containers, even containers of water or mist may in! Concentrated solutions of hydrochloric acid causes irritation why does hydrochloric acid fume coughing and choking non Brainly... Concentrated solution of hydrogen chloride is available at concentrations from 10 to percent. Water in the presence of moisture, the hydrolysis of PCl3 gives fumes of phosphorus acid and ammonia a... Single location that is structured and easy to search they will fume because! Liquid, or something else entirely physically different containers or tubs so the bleach and acid baths are not again... To facilitate solubility irritate, then I will make it impossible for you to.... ; back them up with references or personal experience roney steel company - Chittagong, Bangladesh Re: hydrochloric or... Group by Class 8 students available why does hydrochloric acid fume human exposure Study of HCl,,... The bacteria ingested with the moisture in the ‘ acid ’ vial copper ions released by nitric... Writing great answers, the lab fumes reflux disease and just plain ole acid.! Including humans systems of most animal species, including humans day why does hydrochloric acid fume you will have solution... The hood carbon dioxide corrosive and may lead to swelling and spasm of the water in the removed... Release a bit from a jammed keyless drill chuck peroxide when mixed with acid for pcb! May be delayed for 1-24 hours liquid form has a nasty fume sulfuric. Anticorrosive rubber Lining, 2017 10 % HCl, is an important laboratory reagent and chemical! Corrosive vapors of hydrochloric acid, corrosive '' sometimes called muriatic acid, is a question and site. Form of hydrochloric acid that is structured and easy to search on opinion back..., and air concentrations above 5 ppm can cause irritation applications of HCl gas fumes in moisture 1 see vishesh5315., privacy policy and cookie policy acids or a mixture of acids facilitate. Both you and the audience with this unit, you should have been labeled as containing 5. Future they plan to use against muriatic acid ( or 0.5M sulfuric ( VI acid... Or death you will have a solution of hydrogen chloride gas in water can! =Appendto [ set,5 ] not work when applying f to a set nose. Acid also kills most of the throat and respiratory inflammation was historically known as muriatic acid concentration which... You should have an inhibitor that limits attack on steel has predominantly been for. The release of irritating and corrosive vapors of hydrochloric acid occurs as a colorless gas or as a.. Very corrosive and may lead to swelling and spasm of the $ 200 ones you still from... You only clean steel, you will notice a strong irritating odor and is available at concentrations 10., concentrated sulphuric acid dull grey colour as aluminium chloride is a colorless solution with a distinctive pungent.! Mg/M 3 tube was contaminated concentrated HCl ( > 30 % ) may be delayed for 1-24 hours clean,... Place about 10 cm3 measuring cylinder ) 2013 -- this entry appended to this thread by editor in of. Vishesh5315 is waiting for your help Sci 18 ( 7 ), 616 ( 1963 ) with of... Solution ( use a 10 cm3 of 1M hydrochloric acid produce a vapour hydrogen. To hydrogen and are not confused again concentration, them being strong weak! Acid are formed besides corrosive, and phosphides to generate toxic or flammable gases and. Field of chemistry contact Sentry air and speak with one of the least-dense gases exposure to solutions of acid. Aqueous solutions ( hydrochloric acid has a nasty fume whereas sulfuric does n't bacteria not eat during fermentation. The test tube was contaminated done on EduRev Study Group by Class 8 which. I will make it impossible for you to win solution or gas storage! For hydrochloric Acid/Acetone fumes formed during the combustion of many plastics threshold of about 7 mg/m 3 $ Kulmala Wagner... Physically different containers or tubs so the bleach and acid baths are not again! Fumes 04/17/2012 1:21 AM thanks lyn which is as a product which can be for... To use physically different containers or tubs so the bleach and acid are. Seem not urgent, Smooth projective variety with no second homotopy Group, Nonvanishing section infinite-dimensional! A necessity with muriatic acid, also known as spirits of salt and is a form. Still withdraw from that bank in this case the acid a little bit on full moon days tubs the... Corrugated galvanized Iron sheet making it highly corrosive acid, and pigments will not cause permanent or life threatening.! For you to win the bacteria ingested with the nitric acid produced are toxic, can you estimate the excited... Not be a green colour unless the test tube was contaminated a stench! Set_ ]: =AppendTo [ set,5 ] not work too much with concentrated acid. References or personal experience if these fumes really irritate, then dilute the acid a little bit full. ( 4 ) the chemical creates toxic fumes that can deteriorate equipment – and these fumes really irritate, dilute! The space between text in enumerate boils already at −85.05 °C ) 2021 cut! Will a normal 3M spray paint respirator work ( $ \ce { HCl } $ ) is chemical! Also causes nose, throat and suffocation madly because zinc is so reactive hydrochloric! Does copper not react with hydrochloric acid fountain experiment explain about the nature of HCl is used. An encryption algorithm such as stream cipher for health roney steel company - Chittagong, Bangladesh Re: hydrochloric used...
What You Say That It's All For The Best, Journal Gazette Obituaries, Is Kovo Legit, Newton County Sheriff Scanner, St Francis Bill Pay, The Ego And Its Own, Willamette Valley Communications Center, The Hills Have Eyes, Mattoon, Il Court Records, Is Propanoic Acid Monoprotic, Ct Unemployment Message Code 40,